Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium

• Author(s): Dr. Arvind Prasad Dwivedi ; Shweta Neeraj
• Paper ID: 1700793
• Page: 38-41
• Published Date: 22-11-2018
• Published In: Iconic Research And Engineering Journals
• Publisher: IRE Journals
• e-ISSN: 2456-8880
• Volume/Issue: Volume 2 Issue 5 November-2018

Abstract

The kinetics of reaction between aliphatic ℓ-amino acids and 1,3-dichloro-5,5-dimethylhydantoin have been studied in aqueous acetic acid medium yielding aliphatic aldehydes as the end-products by the ring cleavage oxidation. The catalytic effect of acid in the reaction rate reveal an interaction between oxidants species H2O+Cl and substrates. The observed order of reactivity ℓ-amino acids (ℓ-Glycine > ℓ-Alanine) was explained on the basis of conformational considerations. A plausible mechanism and rate law supported by thermodynamic parameters was discussed.

Keywords

aliphatic aldehydes, demonstrates, reveals, plausible.

Citations

IRE Journals:
Dr. Arvind Prasad Dwivedi , Shweta Neeraj "Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium " Iconic Research And Engineering Journals Volume 2 Issue 5 2018 Page 38-41

IEEE:
Dr. Arvind Prasad Dwivedi , Shweta Neeraj "Oxidative And Thermodynamic Study Of Aliphatic Amino Acids By 1,3-dichloro-5,5-dimethylhydantoin In Aqueous Acetic Acid Medium " Iconic Research And Engineering Journals, 2(5)