Kinetics And Mechanism For The Oxidation Of Co([15]aneN4)(H2O)22+ With Organic Hydroperoxides
Abstract
Thekinetics for the reaction ofCo([15]aneN4)(H2O)22+ with hydroperoxides were studied at lemda= 0.50 M (NaClO4) in 1:1 (v/v) tert-butyl alcohol-water media. The reaction is first order in both CoII complex and hydroperoxide. The reaction rates were effected by varying the alkyl group of the hydroperoxide with the reactivity order being HOOH >C3H7(CH3)2COOH ~ C2H5(CH3)2COOH > (CH3)3COOH. Effect of ionic strength on the oxidation rate has been studied and the reaction mechanism is discussed.
Keywords
Alkylcobalt complexes, Kinetics, Macrocyclic complexes
Citations
IRE Journals:
Shaoyung Lee , Jian-Wei Hwang
"Kinetics And Mechanism For The Oxidation Of Co([15]aneN4)(H2O)22+ With Organic Hydroperoxides" Iconic Research And Engineering Journals Volume 1 Issue 12 2018 Page 33-36
IEEE:
Shaoyung Lee , Jian-Wei Hwang
"Kinetics And Mechanism For The Oxidation Of Co([15]aneN4)(H2O)22+ With Organic Hydroperoxides" Iconic Research And Engineering Journals, 1(12)
About IRE Journals
IRE Journals is an open access online journals established with an aim to publish high quality of research work in various diciplines. We have more than 6 years in publications. Over 2500+ papers already published.
Important Links
For Authors
Volume 7:
Issue 1, Issue 2, Issue 3, Issue 4, Issue 5, Issue 6, Issue 7, Issue 8, Issue 9, Issue 10, Issue 11, Issue 12Volume 6:
Issue 1, Issue 2, Issue 3, Issue 4, Issue 5, Issue 6, Issue 7, Issue 8, Issue 9, Issue 10, Issue 11, Issue 12Volume 5:
Issue 1, Issue 2, Issue 3, Issue 4, Issue 5, Issue 6, Issue 7, Issue 8, Issue 9, Issue 10, Issue 11, Issue 12Volume 4:
Issue 1, Issue 2, Issue 3, Issue 4, Issue 5, Issue 6, Issue 7, Issue 8, Issue 9, Issue 10, Issue 11, Issue 12Volume 3:
Issue 1, Issue 2, Issue 3, Issue 4, Issue 5, Issue 6, Issue 7, Issue 8, Issue 9, Issue 10, Issue 11, Issue 12